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Two Dimensional Triptycene End-Capping and Its Influence on the Self-Assembly of Quinoxalinophenanthrophenazines [Data]
Mar 27, 2023 - Institute of Organic Chemistry - AK Mastalerz
Roß, Lisa; Reitemeier, Julius; Ghalami, Farhad; Zhang, Wen-Shan; Gross, Jürgen H.; Rominger, Frank; Elbert, Sven M.; Schröder, Rasmus; Elstner, Marcus; Mastalerz, Michael, 2023, "Two Dimensional Triptycene End-Capping and Its Influence on the Self-Assembly of Quinoxalinophenanthrophenazines [Data]", https://doi.org/10.11588/data/W3KWEJ, heiDATA, V1
A series of quinoxalinophenanthrophenazines (QPPs) with two-dimensional triptycene end-caps was synthesized from a triphenylene base ortho-diamine. UV/vis spectroscopy suggested the formation of dimers in solution which was further confirmed by MALDI-TIMS-TOF-MS and single crysta...
Desymmetrization Strategy to Achieve Triptycene-Based 3,6-Dimethoxytriphenylenes via Oxidative Cyclodehydrogenation [Data]
Feb 4, 2022 - Institute of Organic Chemistry - AK Mastalerz
Reinhard, Dennis; Rominger, Frank; Mastalerz, Michael, 2022, "Desymmetrization Strategy to Achieve Triptycene-Based 3,6-Dimethoxytriphenylenes via Oxidative Cyclodehydrogenation [Data]", https://doi.org/10.11588/data/OH6757, heiDATA, V1
To achieve a highly symmetric triptycene based hexamethoxytriphenylene in high yield of 97 %, a less symmetric triptycene (C3v) is necessary as precursor for cyclodehydrogenative Scholl-type oxidation, by taking into account the regioselectivity of the C-C bond formation controll...
A Hexagonal Shape-Persistent Nanobelt of Elongated Rhombic Symmetry with Orthogonal π-Planes by a One-Pot Reaction [Data]
Jan 19, 2022 - Institute of Organic Chemistry - AK Mastalerz
Lauer, Jochen C.; Kohl, Bernd; Rominger, Frank; Mastalerz, Michael, 2022, "A Hexagonal Shape-Persistent Nanobelt of Elongated Rhombic Symmetry with Orthogonal π-Planes by a One-Pot Reaction [Data]", https://doi.org/10.11588/data/EBY4AN, heiDATA, V1
Triptycenes with their predefined D3h-symmetry are excellent molecular building blocks to construct shape-persistent nanobelts having π-orbitals orthogonal to the ring plane. However, up to now, there are only a very few examples of fused and rigid iptycene nanobelts synthesized...
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