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Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz
Popp, Dennis; Elbert, Sven Michael; Barwig, Chantal; Petry, Julian; Rominger, Frank; Mastalerz, Michael, 2023, "Palladium-Catalyzed Cyclization of a Pyryne Precursor to Higher Pyrenylenes [Data]",, heiDATA, V1
By palladium-catalyzed oligomerization reactions of pyrene-based o-trimethylsilyl triflates, larger cyclic pyrenylenes were formed with up to 10-membered rings as has been unambiguously characterized by SCXRD. Furthermore, the underlying reaction mechanism has been studied by qua...
Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz
Wagner, Philippe; Rominger, Frank; Gross, Jürgen H.; Mastalerz, Michael, 2023, "Solvent-Controlled Quadruple Catenation of Giant Chiral [8+12] Salicylimine Cubes Driven by Weak Hydrogen Bonding [Data]",, heiDATA, V1
A quadruply interlocked catenane has been formed from giant chiral [8+12] salicylimine cubes in a reaction that can be controlled by the reaction solvent. Single-crystal X-ray diffraction revealed hydrogen bonding to be a central driving force for the catenation. Furthermore, scr...
Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz
Tian, Ke; Wang, Xubin; Schuldt, Moritz P.; Elbert, Sven M.; Rominger, Frank; Mastalerz, Michael, 2023, "[4+4]-Imine Cage Compounds with Nitrogen-Rich Cavities and Tetrahedral Geometry [Data]",, heiDATA, V1
Organic imine cage compounds have found a variety of different applications in several fields in materials science. To design tailor-made cages for corresponding applications, synthetic approaches to cages with tunable functionalities, sizes and shapes have to be found. Here we r...
Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz
Kirschbaum, Tobias; Rominger, Frank; Mastalerz, Michael, 2023, "Synthesis of a Benzotrisazulene via Trioxobenzotrisazulene",, heiDATA, V1
A benzotrisazulene was synthesized on the basis of a truxene precursor by a series of Suzuki–Miyaura reactions via the intermediate trisoxo compound. The latter occurs in two forms (syn and anti), and the syn forms porous crystals.
Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz
Holsten, Mattes; Elbert, Sven Michael; Rominger, Frank; Zhang, Wen-Shan; Schröder, Rasmus R.; Mastalerz, Michael, 2023, "Single Crystals of Insoluble Porous Salicylimine Cages [Data]",, heiDATA, V1
Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus ch...
Aug 8, 2023 - Bunz Group
Zeitter, Nico; Hippchen, Nikolai; Weidlich, Anna; Jäger, Patrick; Ludwig, Philipp; Dr. Rominger, Frank; Dr. Freudenberg, Jan; Prof. Dr. Dreuw, Andreas; Prof. Dr. Bunz, Uwe H. F, 2023, "Hexakis-TIPS-Alkynylated Nonacenes: Persistent and Processible [data]",, heiDATA, V1
We prepared and characterized (UV-vis, epr, X-ray) four substituted nonacenes. They are the most stable and soluble nonacenes to date – due to six strategically placed triisopropylsilyl (TIPS)-ethynyl groups. They are stable for several weeks in the solid state. In dilute solutio...
Jul 24, 2023 - Deschler-Group: Functional Material Dynamics
Liu, Shangpu; Kepenekian, Mikaël; Bodnar, Stanislav; Feldmann, Sascha; Heindl, Markus W.; Fehn, Natalie; Zerhoch, Jonathan; Shcherbakov, Andrii; Pöthig, Alexander; Kartouzian, Aras; Sharp, Ian D.; Katan, Claudine; Even, Jacky; Deschler, Felix, 2023, "Bright Circularly-Polarized Photoluminescence in Chiral Layered Lead-Halide Perovskites [Research Data]",, heiDATA, V1
Hybrid semiconductor materials are predicted to lock chirality into place and encode asymmetry into their electronic states, while the softness of their crystal lattice accommodates lattice strain and maintains high crystal quality with the low defect densities necessary for high...
Deschler-Group: Functional Material Dynamics(Heidelberg University, Institute of Physical Chemistry)
Jul 24, 2023
Open Research Data on functional material dynamics of the Deschler Group at the Institute of Physical Chemistry of Heidelberg University.
Jul 11, 2023 - CryoEM
Wacker, Irene; Curticean, Ronald; Ryklin, Daniel; Weidinger, Britta; Mayer, Frederik; Huang, Li-Yu; Hoffmann, Julian; Islam, Monsur; von Coelln, Nadine; Schmitt, Tanja; Huck, Christian; Tegerder, Petra; Feist, Florian; Kammerer, Jochen A.; Barner-Kowollik, Christopher; Wegener, Martin; Blasco, Eva; Gengenbach, Ulrich; Schröder, Rasmus R., 2023, "Deconstructing 3D Structured Materials by Modern Ultramicrotomy for Multimodal Imaging and Volume Analysis Across Length Scales [Research data and source code]",, heiDATA, V1
Based on the rapid advances in additive manufacturing, micro-patterned heterostructures of soft materials have become available that need to be characterized down to the nanoscale. Advanced function-structure relationships are designed by direct 3D structuring of the object and –...
Jun 12, 2023 - SFB 1249: N-Heteropolyzyklen als Funktionsmaterialien - C: Material & Function
Herrmann, Niklas; von Coelln, Nadine; Teichgreber, Robin M.; Höfener, Sebastian; Huck, Christian; Ghalami, Farhad; Settele, Simon; Hertzog, Manuel; Elstner, Marcus; Tegeder, Petra; Herzig, Eva M.; Zaumseil, Jana, 2023, "Optical and electronic properties of different thin-film polymorphs of PDIF-CN2 controlled by zone-casting conditions [data]",, heiDATA, V1
Underlying data for figures in the paper "Optical and electronic properties of different thin-film polymorphs of PDIF-CN2 controlled by zone-casting conditions"
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