1 to 10 of 20 Results
Mar 20, 2024 - Institute of Organic Chemistry - AK Mastalerz
Yang, Xuan; Brückner, Margit; Rominger, Frank; Kirschbaum, Tobias; Mastalerz, Michael, 2024, "Dispersion-Driven Formation of Chiral Twisted PAH Double Helices [Data]", https://doi.org/10.11588/data/BRM2DI, heiDATA, V1
Molecular double helices are ubiquitous in nature and have also been generated artificially. These are usually based on helical ribbons. Here, a new type of double helices based on twisted ribbons is introduced. The monomeric strands are polycyclic aromatic hydrocarbons of variou... |
Feb 22, 2024 - Institute of Organic Chemistry - AK Mastalerz
Keck, Christoph; Rominger, Frank; Mastalerz, Michael, 2024, "Synthesis of Chiral Pyrene-Based 1,4-Dithiins [Data]", https://doi.org/10.11588/data/NCRUAV, heiDATA, V1
The 1,4-dithiin motif is known for its reversible redox properties to generate radical cations and diradical dications and thus is interesting for organic electronic applications. However, examples where this motif is embedded into chiral larger fused aromatic compounds is very r... |
Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz
Popp, Dennis; Elbert, Sven Michael; Barwig, Chantal; Petry, Julian; Rominger, Frank; Mastalerz, Michael, 2023, "Palladium-Catalyzed Cyclization of a Pyryne Precursor to Higher Pyrenylenes [Data]", https://doi.org/10.11588/data/1TCKKG, heiDATA, V1
By palladium-catalyzed oligomerization reactions of pyrene-based o-trimethylsilyl triflates, larger cyclic pyrenylenes were formed with up to 10-membered rings as has been unambiguously characterized by SCXRD. Furthermore, the underlying reaction mechanism has been studied by qua... |
Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz
Wagner, Philippe; Rominger, Frank; Gross, Jürgen H.; Mastalerz, Michael, 2023, "Solvent-Controlled Quadruple Catenation of Giant Chiral [8+12] Salicylimine Cubes Driven by Weak Hydrogen Bonding [Data]", https://doi.org/10.11588/data/TIYBD2, heiDATA, V1
A quadruply interlocked catenane has been formed from giant chiral [8+12] salicylimine cubes in a reaction that can be controlled by the reaction solvent. Single-crystal X-ray diffraction revealed hydrogen bonding to be a central driving force for the catenation. Furthermore, scr... |
Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz
Tian, Ke; Wang, Xubin; Schuldt, Moritz P.; Elbert, Sven M.; Rominger, Frank; Mastalerz, Michael, 2023, "[4+4]-Imine Cage Compounds with Nitrogen-Rich Cavities and Tetrahedral Geometry [Data]", https://doi.org/10.11588/data/FX6IGS, heiDATA, V1
Organic imine cage compounds have found a variety of different applications in several fields in materials science. To design tailor-made cages for corresponding applications, synthetic approaches to cages with tunable functionalities, sizes and shapes have to be found. Here we r... |
Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz
Kirschbaum, Tobias; Rominger, Frank; Mastalerz, Michael, 2023, "Synthesis of a Benzotrisazulene via Trioxobenzotrisazulene [data]", https://doi.org/10.11588/data/JE8LF7, heiDATA, V1
A benzotrisazulene was synthesized on the basis of a truxene precursor by a series of Suzuki–Miyaura reactions via the intermediate trisoxo compound. The latter occurs in two forms (syn and anti), and the syn forms porous crystals. |
Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz
Holsten, Mattes; Elbert, Sven Michael; Rominger, Frank; Zhang, Wen-Shan; Schröder, Rasmus R.; Mastalerz, Michael, 2023, "Single Crystals of Insoluble Porous Salicylimine Cages [Data]", https://doi.org/10.11588/data/45FZRY, heiDATA, V1
Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus ch... |
Mar 27, 2023 - Institute of Organic Chemistry - AK Mastalerz
Roß, Lisa; Reitemeier, Julius; Ghalami, Farhad; Zhang, Wen-Shan; Gross, Jürgen H.; Rominger, Frank; Elbert, Sven M.; Schröder, Rasmus; Elstner, Marcus; Mastalerz, Michael, 2023, "Two Dimensional Triptycene End-Capping and Its Influence on the Self-Assembly of Quinoxalinophenanthrophenazines [Data]", https://doi.org/10.11588/data/W3KWEJ, heiDATA, V1
A series of quinoxalinophenanthrophenazines (QPPs) with two-dimensional triptycene end-caps was synthesized from a triphenylene base ortho-diamine. UV/vis spectroscopy suggested the formation of dimers in solution which was further confirmed by MALDI-TIMS-TOF-MS and single crysta... |
Dec 14, 2022 - Institute of Organic Chemistry - AK Mastalerz
Benke, Bahiru P.; Kirschbaum, Tobias; Graf, Jürgen; Gross, Jürgen; Mastalerz, Michael, 2022, "Dimeric and Trimeric Catenation of Giant Chiral [8+12] Imine Cubes Driven by Weak Supramolecular Interactions [Data]", https://doi.org/10.11588/data/HI9BJD, heiDATA, V1
Mechanically interlocked structures, such as catenanes or rotaxanes are fascinating synthetic targets and some are used for molecular switches and machines. Today, the vast majority of catenated structures are built upon macrocycles and only a very few examples of three-dimension... |
Dec 5, 2022 - Institute of Organic Chemistry - AK Mastalerz
Lauer, Jochen C.; Bhat, Avinash S.; Barwig, Chantal; Rominger, Frank; Mastalerz, Michael, 2022, "[2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Efficient Nitrate Binding [Data]", https://doi.org/10.11588/data/HWLKZT, heiDATA, V1
The pollution of groundwater with nitrate is a serious issue because nitrate can cause several diseases such as methemoglobinemia or cancer. Therefore, selective removal of nitrate by efficient binding to supramolecular hosts is highly desired. Here we describe how to make [2+3]... |
