1 to 10 of 18 Results
May 8, 2023 - Bunz Group
Ahrens, Lukas; Rominger, Frank; Freudenberg, Jan; Bunz, Uwe H. F., 2023, "Etheno-bridged Azaacene Spiro Dimers [data]", https://doi.org/10.11588/data/L8NDRO, heiDATA, V1
We present the synthesis of two sets of spiro-connected azaacene dimers. Their geometry and electronic coupling are critically determined by a secondary linker, i.e. an etheno- and an ethano-bridge.The core fragment of the etheno-bridged dimer corresponds to a conformationally lo... |
Apr 4, 2023 - Bunz Group
Hippchen, Nikolai; Heinzel, Elena; Zhang, Cathy K.; Jäger, Patrick; Elter, Maximilian; Ludwig, Philipp; Rominger, Frank; Freudenberg, Jan; Cao, Dennis D.; Bunz, Uwe H. F., 2023, "Second Generation of Cata-Annulated Azaacene Bisimides: Towards Electron Accepting Materials [research data]", https://doi.org/10.11588/data/U9IRYY, heiDATA, V1
Herein we provide the reserach data for the puplication: "Second Generation of Cata-Annulated Azaacene Bisimides: Towards Electron Accepting Materials". Where we present the second generation of cata-annulated azaacene bisimides with increased electron affinities compared to thei... |
Mar 27, 2023 - Institute of Organic Chemistry - AK Mastalerz
Roß, Lisa; Reitemeier, Julius; Ghalami, Farhad; Zhang, Wen-Shan; Gross, Jürgen H.; Rominger, Frank; Elbert, Sven M.; Schröder, Rasmus; Elstner, Marcus; Mastalerz, Michael, 2023, "Two Dimensional Triptycene End-Capping and Its Influence on the Self-Assembly of Quinoxalinophenanthrophenazines [Data]", https://doi.org/10.11588/data/W3KWEJ, heiDATA, V1
A series of quinoxalinophenanthrophenazines (QPPs) with two-dimensional triptycene end-caps was synthesized from a triphenylene base ortho-diamine. UV/vis spectroscopy suggested the formation of dimers in solution which was further confirmed by MALDI-TIMS-TOF-MS and single crysta... |
Dec 5, 2022 - Institute of Organic Chemistry - AK Mastalerz
Lauer, Jochen C.; Bhat, Avinash S.; Barwig, Chantal; Rominger, Frank; Mastalerz, Michael, 2022, "[2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Efficient Nitrate Binding [Data]", https://doi.org/10.11588/data/HWLKZT, heiDATA, V1
The pollution of groundwater with nitrate is a serious issue because nitrate can cause several diseases such as methemoglobinemia or cancer. Therefore, selective removal of nitrate by efficient binding to supramolecular hosts is highly desired. Here we describe how to make [2+3]... |
Nov 23, 2022 - Institute of Organic Chemistry - AK Mastalerz
Yang, Xuan; Elbert, Sven Michael; Rominger, Frank; Mastalerz, Michael, 2022, "A Series of Soluble Thieno-fused Coronene Nanoribbons of Precise Lengths [Data]", https://doi.org/10.11588/data/30AOAT, heiDATA, V1
Among graphene nanoribbons (GNRs), reports on coronene-based GNRs were very rare, despite the unique optoelectronic properties of coronene. Herein, the synthesis of a series of structurally precise and soluble thieno-fused coronene nanoribbons (CR-1 to CR-4) with up to four coron... |
Nov 16, 2022 - Institute of Organic Chemistry - AK Mastalerz
Tian, Ke; Elbert, Sven Michael; Hu, Xinyue; Kirschbaum, Tobias; Zhang, Wen-Shan; Rominger, Frank; Schröder, Rasmus R.; Mastalerz, Michael, 2022, "Highly Selective Adsorption of Perfluorinated Greenhouse Gases by Porous Organic Cages [Data]", https://doi.org/10.11588/data/O9I5UP, heiDATA, V1
Anthropogenic greenhouse gases contribute to global warming. Among those gases, perfluorocarbons (PFCs) are thousands to tens of thousands times more harmful to the environment than comparable amounts of carbon dioxide. Till date, materials that selectively adsorb perfluorocarbon... |
Aug 3, 2022 - Bunz Group
Wiesner, Thomas; Wu, Zhu; Han, Jie; Ji, Lei; Friedrich, Alexandra; Krummenacher, Ivo; Moos, Michael; Lambert, Christoph; Braunschweig, Holger; Rudin, Benjamin; Reiss, Hilmar; Tverskoy, Olena; Rominger, Frank; Dreuw, Andreas; Marder, Todd; Freudenberg, Jan; Bunz, Uwe, 2022, "The Radical Anion, Dianion and Electron Transport Properties of Tetraiodo-Tetraazapentacene [Data]", https://doi.org/10.11588/data/S0KS2I, heiDATA, V1
Tetraiodotetraazapentacene I4TAP , the last missing derivative in the series of halogenated silylated tetraazapentacenes, was synthesized via condensation chemistry from a TIPS-ethynylated diaminobenzothiadiazol in three steps. Single and double reduction furnished its air-stable... |
May 2, 2022 - Bunz Group
Zeitter, Nico; Hippchen, Nikolai; Maier, Steffen; Rominger, Frank; Freudenberg, Jan; Bunz, Uwe H. F.; Dreuw, A, 2022, "Persistent Ambipolar Heptacenes and Their Redox Species [Data]", https://doi.org/10.11588/data/CVD7WF, heiDATA, V1
Research Data associated with the related publication. Sixfold TIPS-ethynylation combined with fourfold bromination of the armchair edges furnishes a long-lived, soluble heptacene; π-extension via Stille coupling accesses a persistent tetrabenzononacene. Both types of acenes were... |
Feb 24, 2022 - Bunz Group
Maier, Steffen; Heckershoff, Robin; Wurm, Thomas; Biegger, Philipp; Brödner, Kerstin; Krämer, Petra; Hoffmann, Marvin; Eberle, Lukas; Stein, Jana; Rominger, Frank; Rudolph, Matthias; Freudenberg, Jan; Dreuw, Andreas; Hashmi, Stephen; Bunz, Uwe, 2022, "Cyclopentannulated Dihydrotetraazapentacenes [Data]", https://doi.org/10.11588/data/PZGMSS, heiDATA, V1
The transition-metal catalyzed cyclization of bissilylethynylated N,N’-dihydro¬tetra¬aza¬pentacene (TIPS-TAP-H2) into bissilylated cyclo¬penta¬[fg,qr]¬pentacenes is reported. Depending on the catalyst either none, one or two silyl groups migrate and change their positions in the... |
Feb 4, 2022 - Institute of Organic Chemistry - AK Mastalerz
Reinhard, Dennis; Rominger, Frank; Mastalerz, Michael, 2022, "Desymmetrization Strategy to Achieve Triptycene-Based 3,6-Dimethoxytriphenylenes via Oxidative Cyclodehydrogenation [Data]", https://doi.org/10.11588/data/OH6757, heiDATA, V1
To achieve a highly symmetric triptycene based hexamethoxytriphenylene in high yield of 97 %, a less symmetric triptycene (C3v) is necessary as precursor for cyclodehydrogenative Scholl-type oxidation, by taking into account the regioselectivity of the C-C bond formation controll... |
