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1 to 7 of 7 Results

Soluble Congeners of Prior Insoluble Shape‐Persistent Imine Cages [Data] Jan 17, 2022 - Institute of Organic Chemistry - AK Mastalerz Holsten, Mattes; Feierabend, Sarah; Elbert, Sven M.; Rominger, Frank; Oeser, Thomas; Mastalerz, Michael, 2022, "Soluble Congeners of Prior Insoluble Shape‐Persistent Imine Cages [Data]", https://doi.org/10.11588/data/E2RPGA, heiDATA, V1 One of the most applied reaction types to synthesize shape‐persistent organic cage compounds is the imine condensation reaction and it is assumed that the formed cages are thermodynamically controlled products due to the reversibility of the imine condensation. However, most of t...
Single Crystals of Insoluble Porous Salicylimine Cages [Data] Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz Holsten, Mattes; Elbert, Sven Michael; Rominger, Frank; Zhang, Wen-Shan; Schröder, Rasmus R.; Mastalerz, Michael, 2023, "Single Crystals of Insoluble Porous Salicylimine Cages [Data]", https://doi.org/10.11588/data/45FZRY, heiDATA, V1 Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus ch...
Highly Selective Adsorption of Perfluorinated Greenhouse Gases by Porous Organic Cages [Data] Nov 16, 2022 - Institute of Organic Chemistry - AK Mastalerz Tian, Ke; Elbert, Sven Michael; Hu, Xinyue; Kirschbaum, Tobias; Zhang, Wen-Shan; Rominger, Frank; Schröder, Rasmus R.; Mastalerz, Michael, 2022, "Highly Selective Adsorption of Perfluorinated Greenhouse Gases by Porous Organic Cages [Data]", https://doi.org/10.11588/data/O9I5UP, heiDATA, V1 Anthropogenic greenhouse gases contribute to global warming. Among those gases, perfluorocarbons (PFCs) are thousands to tens of thousands times more harmful to the environment than comparable amounts of carbon dioxide. Till date, materials that selectively adsorb perfluorocarbon...
Cyclopentannulated Dihydrotetraazapentacenes [Data] Feb 24, 2022 - Bunz Group Maier, Steffen; Heckershoff, Robin; Wurm, Thomas; Biegger, Philipp; Brödner, Kerstin; Krämer, Petra; Hoffmann, Marvin; Eberle, Lukas; Stein, Jana; Rominger, Frank; Rudolph, Matthias; Freudenberg, Jan; Dreuw, Andreas; Hashmi, Stephen; Bunz, Uwe, 2022, "Cyclopentannulated Dihydrotetraazapentacenes [Data]", https://doi.org/10.11588/data/PZGMSS, heiDATA, V1 The transition-metal catalyzed cyclization of bissilylethynylated N,N’-dihydro¬tetra¬aza¬pentacene (TIPS-TAP-H2) into bissilylated cyclo¬penta¬[fg,qr]¬pentacenes is reported. Depending on the catalyst either none, one or two silyl groups migrate and change their positions in the...
Benzo-Fused Perylene Oligomers with up to 13 Linearly Annulated Rings [Data] Jan 20, 2022 - Institute of Organic Chemistry - AK Mastalerz Yang, Xuan; Rominger, Frank; Mastalerz, Michael, 2022, "Benzo-Fused Perylene Oligomers with up to 13 Linearly Annulated Rings [Data]", https://doi.org/10.11588/data/2TX0VD, heiDATA, V1 The longer acenes with more than six linearly fused six-membered rings are still fascinating chemists and physicists because of their unique photophysical properties and their high potential for organic electronics applications. Unfortunately, with increasing size (seven and more...
A Series of Soluble Thieno-fused Coronene Nanoribbons of Precise Lengths [Data] Nov 23, 2022 - Institute of Organic Chemistry - AK Mastalerz Yang, Xuan; Elbert, Sven Michael; Rominger, Frank; Mastalerz, Michael, 2022, "A Series of Soluble Thieno-fused Coronene Nanoribbons of Precise Lengths [Data]", https://doi.org/10.11588/data/30AOAT, heiDATA, V1 Among graphene nanoribbons (GNRs), reports on coronene-based GNRs were very rare, despite the unique optoelectronic properties of coronene. Herein, the synthesis of a series of structurally precise and soluble thieno-fused coronene nanoribbons (CR-1 to CR-4) with up to four coron...
[2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Efficient Nitrate Binding [Data] Dec 5, 2022 - Institute of Organic Chemistry - AK Mastalerz Lauer, Jochen C.; Bhat, Avinash S.; Barwig, Chantal; Rominger, Frank; Mastalerz, Michael, 2022, "[2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Efficient Nitrate Binding [Data]", https://doi.org/10.11588/data/HWLKZT, heiDATA, V1 The pollution of groundwater with nitrate is a serious issue because nitrate can cause several diseases such as methemoglobinemia or cancer. Therefore, selective removal of nitrate by efficient binding to supramolecular hosts is highly desired. Here we describe how to make [2+3]...

Soluble Congeners of Prior Insoluble Shape‐Persistent Imine Cages [Data]

Jan 17, 2022 - Institute of Organic Chemistry - AK Mastalerz

Holsten, Mattes; Feierabend, Sarah; Elbert, Sven M.; Rominger, Frank; Oeser, Thomas; Mastalerz, Michael, 2022, "Soluble Congeners of Prior Insoluble Shape‐Persistent Imine Cages [Data]", https://doi.org/10.11588/data/E2RPGA, heiDATA, V1

One of the most applied reaction types to synthesize shape‐persistent organic cage compounds is the imine condensation reaction and it is assumed that the formed cages are thermodynamically controlled products due to the reversibility of the imine condensation. However, most of t...

Single Crystals of Insoluble Porous Salicylimine Cages [Data]

Aug 23, 2023 - Institute of Organic Chemistry - AK Mastalerz

Holsten, Mattes; Elbert, Sven Michael; Rominger, Frank; Zhang, Wen-Shan; Schröder, Rasmus R.; Mastalerz, Michael, 2023, "Single Crystals of Insoluble Porous Salicylimine Cages [Data]", https://doi.org/10.11588/data/45FZRY, heiDATA, V1

Porous organic cages (POCs) are meanwhile an established class of porous materials. Most of them are soluble to a certain extend and thus processable in or from solution. However, a few of larger salicylimine cages were reported to be insoluble in any organic solvents and thus ch...

Highly Selective Adsorption of Perfluorinated Greenhouse Gases by Porous Organic Cages [Data]

Nov 16, 2022 - Institute of Organic Chemistry - AK Mastalerz

Tian, Ke; Elbert, Sven Michael; Hu, Xinyue; Kirschbaum, Tobias; Zhang, Wen-Shan; Rominger, Frank; Schröder, Rasmus R.; Mastalerz, Michael, 2022, "Highly Selective Adsorption of Perfluorinated Greenhouse Gases by Porous Organic Cages [Data]", https://doi.org/10.11588/data/O9I5UP, heiDATA, V1

Anthropogenic greenhouse gases contribute to global warming. Among those gases, perfluorocarbons (PFCs) are thousands to tens of thousands times more harmful to the environment than comparable amounts of carbon dioxide. Till date, materials that selectively adsorb perfluorocarbon...

Cyclopentannulated Dihydrotetraazapentacenes [Data]

Feb 24, 2022 - Bunz Group

Maier, Steffen; Heckershoff, Robin; Wurm, Thomas; Biegger, Philipp; Brödner, Kerstin; Krämer, Petra; Hoffmann, Marvin; Eberle, Lukas; Stein, Jana; Rominger, Frank; Rudolph, Matthias; Freudenberg, Jan; Dreuw, Andreas; Hashmi, Stephen; Bunz, Uwe, 2022, "Cyclopentannulated Dihydrotetraazapentacenes [Data]", https://doi.org/10.11588/data/PZGMSS, heiDATA, V1

The transition-metal catalyzed cyclization of bissilylethynylated N,N’-dihydro¬tetra¬aza¬pentacene (TIPS-TAP-H2) into bissilylated cyclo¬penta¬[fg,qr]¬pentacenes is reported. Depending on the catalyst either none, one or two silyl groups migrate and change their positions in the...

Benzo-Fused Perylene Oligomers with up to 13 Linearly Annulated Rings [Data]

Jan 20, 2022 - Institute of Organic Chemistry - AK Mastalerz

Yang, Xuan; Rominger, Frank; Mastalerz, Michael, 2022, "Benzo-Fused Perylene Oligomers with up to 13 Linearly Annulated Rings [Data]", https://doi.org/10.11588/data/2TX0VD, heiDATA, V1

The longer acenes with more than six linearly fused six-membered rings are still fascinating chemists and physicists because of their unique photophysical properties and their high potential for organic electronics applications. Unfortunately, with increasing size (seven and more...

A Series of Soluble Thieno-fused Coronene Nanoribbons of Precise Lengths [Data]

Nov 23, 2022 - Institute of Organic Chemistry - AK Mastalerz

Yang, Xuan; Elbert, Sven Michael; Rominger, Frank; Mastalerz, Michael, 2022, "A Series of Soluble Thieno-fused Coronene Nanoribbons of Precise Lengths [Data]", https://doi.org/10.11588/data/30AOAT, heiDATA, V1

Among graphene nanoribbons (GNRs), reports on coronene-based GNRs were very rare, despite the unique optoelectronic properties of coronene. Herein, the synthesis of a series of structurally precise and soluble thieno-fused coronene nanoribbons (CR-1 to CR-4) with up to four coron...

[2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Efficient Nitrate Binding [Data]

Dec 5, 2022 - Institute of Organic Chemistry - AK Mastalerz

Lauer, Jochen C.; Bhat, Avinash S.; Barwig, Chantal; Rominger, Frank; Mastalerz, Michael, 2022, "[2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Efficient Nitrate Binding [Data]", https://doi.org/10.11588/data/HWLKZT, heiDATA, V1

The pollution of groundwater with nitrate is a serious issue because nitrate can cause several diseases such as methemoglobinemia or cancer. Therefore, selective removal of nitrate by efficient binding to supramolecular hosts is highly desired. Here we describe how to make [2+3]...

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