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Dispersion-Driven Formation of Chiral Twisted PAH Double Helices [Data]
Mar 20, 2024
Yang, Xuan; Brückner, Margit; Rominger, Frank; Kirschbaum, Tobias; Mastalerz, Michael, 2024, "Dispersion-Driven Formation of Chiral Twisted PAH Double Helices [Data]", https://doi.org/10.11588/data/BRM2DI, heiDATA, V1
Molecular double helices are ubiquitous in nature and have also been generated artificially. These are usually based on helical ribbons. Here, a new type of double helices based on twisted ribbons is introduced. The monomeric strands are polycyclic aromatic hydrocarbons of variou...
Chirale polyzyklische aromatische Kohlenwasserstoffe mit Affensattel-Topologie [Data]
Dec 5, 2022 - AK Mastalerz- PhD related Material
Kirschbaum, Tobias, 2022, "Chirale polyzyklische aromatische Kohlenwasserstoffe mit Affensattel-Topologie [Data]", https://doi.org/10.11588/data/SHVINO, heiDATA, V1
In this thesis, the first chiral polycyclic aromatic hydrocarbon (PAH) with a monkey saddle topology is presented. Starting from a truxene building block that is readily preparatively accessible, the monkey saddle PAH could easily be obtained in three steps. By using additional f...
A Triptycene-Based Enantiopure Bis(Diazadibenzoanthracene) by a Chirality-Assisted Synthesis Approach [Data]
Jan 19, 2022
Wang, Xubin; Kohl, Bernd; Rominger, Frank; Elbert, Sven Michael; Mastalerz, Michael, 2022, "A Triptycene-Based Enantiopure Bis(Diazadibenzoanthracene) by a Chirality-Assisted Synthesis Approach [Data]", https://doi.org/10.11588/data/46LINE, heiDATA, V1
By applying a chirality-assisted synthesis (CAS)approach enantiopure diaminodibromotriptycenes were converted to rigid chiral helical diazadibenzoanthracenes, which show besides pronounced Cotton effects in circular dichroism spectra higher photoluminescence quantum yields as com...
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