3D Matter Made to Order (3DMM2O)

Data publications from the Cluster of Excellence 3D Matter Made to Order (3DMM2O). The Cluster is a collaboration of Karlsruhe Institute of Technology (KIT) and Heidelberg University. It pursues an interdisciplinary approach through conjunction of natural, engineering, and social sciences. 3DMM2O establishes scalable digital 3D Additive Manufacturing transcending from the molecular to the macroscopic scale. The goal is the ultimate digitalization of 3D manufacturing and material processing.

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1 to 10 of 28 Results

A Facile Approach for 4D Microprinting of Multi-Photoresponsive Actuators [data] Nov 2, 2022 - Blasco Group Hsu, Li-Yun; Mainik, Philipp; Münchinger, Alexander; Lindenthal, Sebastian; Spratte, Tobias; Welle, Alexander; Zaumseil, Jana; Selhuber-Unkel, Christine; Wegener, Martin; Blasco, Eva, 2022, "A Facile Approach for 4D Microprinting of Multi-Photoresponsive Actuators [data]", https://doi.org/10.11588/data/MR5H4A, heiDATA, V1 For microscale 4D photoresponsive actuators, light is crucial in two ways. First, the underlying additive manufacturing techniques rely on photopolymerization processes triggered by the absorption of light. Second, the absorption of light serves as the actuation stimulus. The two...
A Hexagonal Shape-Persistent Nanobelt of Elongated Rhombic Symmetry with Orthogonal π-Planes by a One-Pot Reaction [Data] Jan 19, 2022 - Institute of Organic Chemistry - AK Mastalerz Lauer, Jochen C.; Kohl, Bernd; Rominger, Frank; Mastalerz, Michael, 2022, "A Hexagonal Shape-Persistent Nanobelt of Elongated Rhombic Symmetry with Orthogonal π-Planes by a One-Pot Reaction [Data]", https://doi.org/10.11588/data/EBY4AN, heiDATA, V1 Triptycenes with their predefined D3h-symmetry are excellent molecular building blocks to construct shape-persistent nanobelts having π-orbitals orthogonal to the ring plane. However, up to now, there are only a very few examples of fused and rigid iptycene nanobelts synthesized...
A Minimalistic, Synthetic Cell-Inspired Metamaterial for Enabling Reversible Strain-Stiffening [data] Feb 16, 2024 Taale, Mohammadreza, 2024, "A Minimalistic, Synthetic Cell-Inspired Metamaterial for Enabling Reversible Strain-Stiffening [data]", https://doi.org/10.11588/data/MNMLVX, heiDATA, V1 Strain-stiffening, i.e. the nonlinear stiffening of a material in response to a strain, is an intrinsic feature of many biological systems, including skin, blood vessels, and single cells. To avoid a mismatch in mechanical properties, synthetic materials in contact with such biol...
A Triptycene-Based Enantiopure Bis(Diazadibenzoanthracene) by a Chirality-Assisted Synthesis Approach [Data] Jan 19, 2022 - Institute of Organic Chemistry - AK Mastalerz Wang, Xubin; Kohl, Bernd; Rominger, Frank; Elbert, Sven Michael; Mastalerz, Michael, 2022, "A Triptycene-Based Enantiopure Bis(Diazadibenzoanthracene) by a Chirality-Assisted Synthesis Approach [Data]", https://doi.org/10.11588/data/46LINE, heiDATA, V1 By applying a chirality-assisted synthesis (CAS)approach enantiopure diaminodibromotriptycenes were converted to rigid chiral helical diazadibenzoanthracenes, which show besides pronounced Cotton effects in circular dichroism spectra higher photoluminescence quantum yields as com...
An Engineered β-Hairpin Peptide Forming Thermostable Complexes with ZnII, NiII, and CuII through a His3 Site [Research Data] Feb 19, 2024 - Thomas Lab Pham, Truc Lam; Fazliev, Sunnatullo; Baur, Philipp; Comba, Peter; Thomas, Franziska, 2024, "An Engineered β-Hairpin Peptide Forming Thermostable Complexes with ZnII, NiII, and CuII through a His3 Site [Research Data]", https://doi.org/10.11588/data/SIESG0, heiDATA, V1 The three-dimensional structure of a peptide, which determines its function, can denature at elevated temperatures, in the presence of chaotropic reagents, or in organic solvents. These factors limit the applicability of peptides. Herein, we present an engineered β-hairpin peptid...
Aqueous seeded RAFT polymerization for the preparation of self-assemblies containing nucleobase analogues [data] Feb 1, 2023 - Blasco Group Miriam Abad; Martina Nardi; Luis Oriol; Milagros Piñol; Eva Blasco, 2023, "Aqueous seeded RAFT polymerization for the preparation of self-assemblies containing nucleobase analogues [data]", https://doi.org/10.11588/data/U1O0NB, heiDATA, V1 Self-assemblies containing the nucleobase analogue 2,6-diacylaminopyridine (DAP) have been successfully prepared for the first time by aqueous seeded RAFT polymerization in high concentrations. For this purpose, a diblock copolymer containing poly(ethylene glycol) (PEG) and DAP p...
Designing Sustainable Polymers: Lactate Esters for 3D Printing and Upcycling [data] Oct 13, 2023 - Blasco Group Klee, Pia S.; Vazquez-Martel, Clara; Florido Martins, Lilliana; Blasco, Eva, 2023, "Designing Sustainable Polymers: Lactate Esters for 3D Printing and Upcycling [data]", https://doi.org/10.11588/data/NUIXMG, heiDATA, V1 The search for sustainable polymer systems is key to tackling the current climate crisis. However, the use of bio-based polymers does not suffice to achieve this goal. Additionally, new chemical approaches enabling the re- or upcycling of polymer materials need to be explored. He...
Desymmetrization Strategy to Achieve Triptycene-Based 3,6-Dimethoxytriphenylenes via Oxidative Cyclodehydrogenation [Data] Feb 4, 2022 - Institute of Organic Chemistry - AK Mastalerz Reinhard, Dennis; Rominger, Frank; Mastalerz, Michael, 2022, "Desymmetrization Strategy to Achieve Triptycene-Based 3,6-Dimethoxytriphenylenes via Oxidative Cyclodehydrogenation [Data]", https://doi.org/10.11588/data/OH6757, heiDATA, V1 To achieve a highly symmetric triptycene based hexamethoxytriphenylene in high yield of 97 %, a less symmetric triptycene (C3v) is necessary as precursor for cyclodehydrogenative Scholl-type oxidation, by taking into account the regioselectivity of the C-C bond formation controll...
Dual kinetic and structural role for the surface in guiding SAS-6 self-assembly to direct centriole architecture [Data] Sep 23, 2021 de Buhr, Svenja; Gräter, Frauke, 2021, "Dual kinetic and structural role for the surface in guiding SAS-6 self-assembly to direct centriole architecture [Data]", https://doi.org/10.11588/data/3NKHAY, heiDATA, V1 This dataset contains input structures and parameters for coarse-grained molecular dynamics simulation of SAS-6 protein oligomers as well as post-processing files and analysis scripts. Abstract of related publication: Discovering mechanisms governing organelle assembly is a funda...
Electron-beam lithography of cinnamate polythiophene films: conductive nanorods for electronic applications [Data] Jul 5, 2022 - Bunz Group Bojanowski, N. Maximilian; Huck, Christian; Veith, Lisa; Strunk, Karl-Philipp; Bäuerle, Rainer; Melzer, Christian; Freudenberg, Jan; Wacker, Irene; Schröder, Rasmus R.; Tegeder, Petra; Bunz, Uwe H. F., 2022, "Electron-beam lithography of cinnamate polythiophene films: conductive nanorods for electronic applications [Data]", https://doi.org/10.11588/data/ZJAT9A, heiDATA, V1 Research Data associated with the related publication. Synthesis and characterization of cinnamate substituted polythiophene (P3ZT). Cross linkage via UV and electron beam radiation; network formation in thin films controlled by infrared spectroscopy and film retention experiment...

A Facile Approach for 4D Microprinting of Multi-Photoresponsive Actuators [data]

Nov 2, 2022 - Blasco Group

Hsu, Li-Yun; Mainik, Philipp; Münchinger, Alexander; Lindenthal, Sebastian; Spratte, Tobias; Welle, Alexander; Zaumseil, Jana; Selhuber-Unkel, Christine; Wegener, Martin; Blasco, Eva, 2022, "A Facile Approach for 4D Microprinting of Multi-Photoresponsive Actuators [data]", https://doi.org/10.11588/data/MR5H4A, heiDATA, V1

For microscale 4D photoresponsive actuators, light is crucial in two ways. First, the underlying additive manufacturing techniques rely on photopolymerization processes triggered by the absorption of light. Second, the absorption of light serves as the actuation stimulus. The two...

A Hexagonal Shape-Persistent Nanobelt of Elongated Rhombic Symmetry with Orthogonal π-Planes by a One-Pot Reaction [Data]

Jan 19, 2022 - Institute of Organic Chemistry - AK Mastalerz

Lauer, Jochen C.; Kohl, Bernd; Rominger, Frank; Mastalerz, Michael, 2022, "A Hexagonal Shape-Persistent Nanobelt of Elongated Rhombic Symmetry with Orthogonal π-Planes by a One-Pot Reaction [Data]", https://doi.org/10.11588/data/EBY4AN, heiDATA, V1

Triptycenes with their predefined D3h-symmetry are excellent molecular building blocks to construct shape-persistent nanobelts having π-orbitals orthogonal to the ring plane. However, up to now, there are only a very few examples of fused and rigid iptycene nanobelts synthesized...

A Minimalistic, Synthetic Cell-Inspired Metamaterial for Enabling Reversible Strain-Stiffening [data]

Feb 16, 2024

Taale, Mohammadreza, 2024, "A Minimalistic, Synthetic Cell-Inspired Metamaterial for Enabling Reversible Strain-Stiffening [data]", https://doi.org/10.11588/data/MNMLVX, heiDATA, V1

Strain-stiffening, i.e. the nonlinear stiffening of a material in response to a strain, is an intrinsic feature of many biological systems, including skin, blood vessels, and single cells. To avoid a mismatch in mechanical properties, synthetic materials in contact with such biol...

A Triptycene-Based Enantiopure Bis(Diazadibenzoanthracene) by a Chirality-Assisted Synthesis Approach [Data]

Jan 19, 2022 - Institute of Organic Chemistry - AK Mastalerz

Wang, Xubin; Kohl, Bernd; Rominger, Frank; Elbert, Sven Michael; Mastalerz, Michael, 2022, "A Triptycene-Based Enantiopure Bis(Diazadibenzoanthracene) by a Chirality-Assisted Synthesis Approach [Data]", https://doi.org/10.11588/data/46LINE, heiDATA, V1

By applying a chirality-assisted synthesis (CAS)approach enantiopure diaminodibromotriptycenes were converted to rigid chiral helical diazadibenzoanthracenes, which show besides pronounced Cotton effects in circular dichroism spectra higher photoluminescence quantum yields as com...

An Engineered β-Hairpin Peptide Forming Thermostable Complexes with ZnII, NiII, and CuII through a His3 Site [Research Data]

Feb 19, 2024 - Thomas Lab

Pham, Truc Lam; Fazliev, Sunnatullo; Baur, Philipp; Comba, Peter; Thomas, Franziska, 2024, "An Engineered β-Hairpin Peptide Forming Thermostable Complexes with ZnII, NiII, and CuII through a His3 Site [Research Data]", https://doi.org/10.11588/data/SIESG0, heiDATA, V1

The three-dimensional structure of a peptide, which determines its function, can denature at elevated temperatures, in the presence of chaotropic reagents, or in organic solvents. These factors limit the applicability of peptides. Herein, we present an engineered β-hairpin peptid...

Aqueous seeded RAFT polymerization for the preparation of self-assemblies containing nucleobase analogues [data]

Feb 1, 2023 - Blasco Group

Miriam Abad; Martina Nardi; Luis Oriol; Milagros Piñol; Eva Blasco, 2023, "Aqueous seeded RAFT polymerization for the preparation of self-assemblies containing nucleobase analogues [data]", https://doi.org/10.11588/data/U1O0NB, heiDATA, V1

Self-assemblies containing the nucleobase analogue 2,6-diacylaminopyridine (DAP) have been successfully prepared for the first time by aqueous seeded RAFT polymerization in high concentrations. For this purpose, a diblock copolymer containing poly(ethylene glycol) (PEG) and DAP p...

Designing Sustainable Polymers: Lactate Esters for 3D Printing and Upcycling [data]

Oct 13, 2023 - Blasco Group

Klee, Pia S.; Vazquez-Martel, Clara; Florido Martins, Lilliana; Blasco, Eva, 2023, "Designing Sustainable Polymers: Lactate Esters for 3D Printing and Upcycling [data]", https://doi.org/10.11588/data/NUIXMG, heiDATA, V1

The search for sustainable polymer systems is key to tackling the current climate crisis. However, the use of bio-based polymers does not suffice to achieve this goal. Additionally, new chemical approaches enabling the re- or upcycling of polymer materials need to be explored. He...

Desymmetrization Strategy to Achieve Triptycene-Based 3,6-Dimethoxytriphenylenes via Oxidative Cyclodehydrogenation [Data]

Feb 4, 2022 - Institute of Organic Chemistry - AK Mastalerz

Reinhard, Dennis; Rominger, Frank; Mastalerz, Michael, 2022, "Desymmetrization Strategy to Achieve Triptycene-Based 3,6-Dimethoxytriphenylenes via Oxidative Cyclodehydrogenation [Data]", https://doi.org/10.11588/data/OH6757, heiDATA, V1

To achieve a highly symmetric triptycene based hexamethoxytriphenylene in high yield of 97 %, a less symmetric triptycene (C3v) is necessary as precursor for cyclodehydrogenative Scholl-type oxidation, by taking into account the regioselectivity of the C-C bond formation controll...

Dual kinetic and structural role for the surface in guiding SAS-6 self-assembly to direct centriole architecture [Data]

Sep 23, 2021

de Buhr, Svenja; Gräter, Frauke, 2021, "Dual kinetic and structural role for the surface in guiding SAS-6 self-assembly to direct centriole architecture [Data]", https://doi.org/10.11588/data/3NKHAY, heiDATA, V1

This dataset contains input structures and parameters for coarse-grained molecular dynamics simulation of SAS-6 protein oligomers as well as post-processing files and analysis scripts. Abstract of related publication: Discovering mechanisms governing organelle assembly is a funda...

Electron-beam lithography of cinnamate polythiophene films: conductive nanorods for electronic applications [Data]

Jul 5, 2022 - Bunz Group

Bojanowski, N. Maximilian; Huck, Christian; Veith, Lisa; Strunk, Karl-Philipp; Bäuerle, Rainer; Melzer, Christian; Freudenberg, Jan; Wacker, Irene; Schröder, Rasmus R.; Tegeder, Petra; Bunz, Uwe H. F., 2022, "Electron-beam lithography of cinnamate polythiophene films: conductive nanorods for electronic applications [Data]", https://doi.org/10.11588/data/ZJAT9A, heiDATA, V1

Research Data associated with the related publication. Synthesis and characterization of cinnamate substituted polythiophene (P3ZT). Cross linkage via UV and electron beam radiation; network formation in thin films controlled by infrared spectroscopy and film retention experiment...

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