Benzo-Fused Perylene Oligomers with up to 13 Linearly Annulated Rings [Data]doi:10.11588/data/2TX0VDheiDATA2022-01-201Yang, Xuan; Rominger, Frank; Mastalerz, Michael, 2022, "Benzo-Fused Perylene Oligomers with up to 13 Linearly Annulated Rings [Data]", https://doi.org/10.11588/data/2TX0VD, heiDATA, V1Benzo-Fused Perylene Oligomers with up to 13 Linearly Annulated Rings [Data]doi:10.11588/data/2TX0VDYang, XuanRominger, FrankMastalerz, MichaelSFB 1249 (TP-A04)heiDATAMastalerz, MichaelChemistryacenescondensationfluorescenceperi-annulationpolycyclic aromatic hydrocarbonsThe longer acenes with more than six linearly fused six-membered rings are still fascinating chemists and physicists because of their unique photophysical properties and their high potential for organic electronics applications. Unfortunately, with increasing size (seven and more rings) these compounds rapidly lose chemical stability. Besides kinetic and chemical stabilization approaches introducing either bulky or electron-withdrawing groups or both, such systems also have been stabilized by peri-annulation. Although strictly spoken, these peri-annulated compounds are no longer real acenes, they have fascinating properties as well. Herein, we describe the first synthesis of a new series of peri-annulated acenes with up to 13 linearly fused rings, which is unprecedented till date. Furthermore, this new series contains perylene units connected through benzene rings along their [b,k]edges, responsible for unique absorption and emission properties.Angew. Chem. Int. Ed. 2021, 60, 7941–7946.10.1002/anie.202017062Angew. Chem. Int. Ed. 2021, 60, 7941–7946.Compound 10_XY403 XY413.zipapplication/zipCompound 11_XY405.zipapplication/zipCompound 2_XY366.zipapplication/zipCompound 3_XY409.zipapplication/zipCompound 4_XY371.zipapplication/zipCompound 5_XY359 XY430.zipapplication/zipCompound 6_XY369 XY525 XY661.zipapplication/zipCompound 7_XY390 XY523.zipapplication/zipCompound 8_XY376 XY431.zipapplication/zipCompound 9_XY406.zipapplication/zipCompound PO-13 XY763.zipapplication/zipCompound PO-17-impure_XY529.zipapplication/zipCompound PO-5_XY377 XY411.zipapplication/zipCompound PO-9_XY370.zipapplication/zipCompound S3_XY372.zipapplication/zip