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Part 1: Document Description
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Citation |
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Title: |
Soluble Congeners of Prior Insoluble Shape‐Persistent Imine Cages [Data] |
Identification Number: |
doi:10.11588/data/E2RPGA |
Distributor: |
heiDATA |
Date of Distribution: |
2022-01-17 |
Version: |
1 |
Bibliographic Citation: |
Holsten, Mattes; Feierabend, Sarah; Elbert, Sven M.; Rominger, Frank; Oeser, Thomas; Mastalerz, Michael, 2022, "Soluble Congeners of Prior Insoluble Shape‐Persistent Imine Cages [Data]", https://doi.org/10.11588/data/E2RPGA, heiDATA, V1 |
Citation |
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Title: |
Soluble Congeners of Prior Insoluble Shape‐Persistent Imine Cages [Data] |
Identification Number: |
doi:10.11588/data/E2RPGA |
Authoring Entity: |
Holsten, Mattes (Institute of Organic Chemistry, Heidelberg University) |
Feierabend, Sarah (Institute of Organic Chemistry, Heidelberg University) |
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Elbert, Sven M. (Institute of Organic Chemistry, Heidelberg University) |
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Rominger, Frank (Institute of Organic Chemistry, Heidelberg University) |
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Oeser, Thomas (Institute of Organic Chemistry, Heidelberg University) |
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Mastalerz, Michael (Institute of Organic Chemistry, Heidelberg University) |
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Software used in Production: |
MestReNova |
Software used in Production: |
Microsoft Excel |
Software used in Production: |
OriginPro 2020 |
Software used in Production: |
OPUS |
Software used in Production: |
TopSpin |
Grant Number: |
725765 |
Grant Number: |
EXC-2082/1 - 390761711 |
Distributor: |
heiDATA |
Access Authority: |
Mastalerz, Michael |
Holdings Information: |
https://doi.org/10.11588/data/E2RPGA |
Study Scope |
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Keywords: |
Chemistry |
Abstract: |
One of the most applied reaction types to synthesize shape‐persistent organic cage compounds is the imine condensation reaction and it is assumed that the formed cages are thermodynamically controlled products due to the reversibility of the imine condensation. However, most of the synthesized imine cages reported are formed as precipitate from the reaction mixture and therefore rather may be kinetically controlled products. There are even examples in literature, where resulting cages are not soluble at all in common organic solvents to characterize or study their formation by NMR spectroscopy in solution. Here, a triptycene triamine containing three solubilizing n‐hexyloxy chains has been used to synthesize soluble congeners of prior insoluble cages. This allowed us to study the formation as well the reversibility of cage formation in solution by investigating exchange of building blocks between the cages and deuterated derivatives thereof. |
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Data Access |
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Other Study Description Materials |
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Related Publications |
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Citation |
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Title: |
M. Holsten, S. Feierabend, S. M. Elbert, F. Rominger, T. Oeser, M. Mastalerz, Chem. Eur. J. 2021, 27, 9383. |
Identification Number: |
10.1002/chem.202100666 |
Bibliographic Citation: |
M. Holsten, S. Feierabend, S. M. Elbert, F. Rominger, T. Oeser, M. Mastalerz, Chem. Eur. J. 2021, 27, 9383. |
Label: |
Compound 11-d156.zip |
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Compound 11.zip |
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Compound 12-d156.zip |
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Compound 12.zip |
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Compound 13-d156.zip |
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Compound 13.zip |
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Compound 14-d156.zip |
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Compound 14.zip |
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Compound 5-d39.zip |
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Compound 5.zip |
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Compound 6-d39.zip |
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Compound 6.zip |
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Compound 7a-d39.zip |
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Compound 7a.zip |
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Compound 7b.zip |
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Exchange Experiments.zip |
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Monitoring of Cage Formations.zip |
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Readme.txt |
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VT NMR Experiments.zip |
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